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formic acid : ウィキペディア英語版
formic acid

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Formic acid (also called methanoic acid) is the simplest carboxylic acid. Its chemical formula is HCOOH or HCO2H. It is an important intermediate in chemical synthesis and occurs naturally, most notably in some ants. Its name comes from the Latin word for ant, ''formica'', referring to its early isolation by the distillation of ant bodies. Esters, salts, and the anions derived from formic acid are referred to as formates.
==Properties==

Formic acid is a colorless liquid having a highly pungent, penetrating odor〔().〕 at room temperature. It is miscible with water and most polar organic solvents, and is somewhat soluble in hydrocarbons. In hydrocarbons and in the vapor phase, it consists of hydrogen-bonded dimers rather than individual molecules.〔Werner Reutemann and Heinz Kieczka "Formic Acid" in ''Ullmann's Encyclopedia of Industrial Chemistry'' 2002, Wiley-VCH, Weinheim. 〕 Owing to its tendency to hydrogen-bond, gaseous formic acid does not obey the ideal gas law.〔 Solid formic acid (two polymorphs) consists of an effectively endless network of hydrogen-bonded formic acid molecules. This relatively complicated compound also forms a low-boiling azeotrope with water (22.4%) and liquid formic acid also tends to supercool.


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